KINETICS OF THE ESTERIFICATION OF PALMITIC ACID WITH ISOBUTYL ALCOHOL

被引：29
|
作者：
GOTO, S
TAGAWA, T
YUSOFF, A
机构：
[1] Department of Chemical Engineering, Nagoya University, Nagoya, 464-01, Chikusa
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1991年 / 23卷 / 01期
关键词：
D O I：
10.1002/kin.550230103
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Kinetics of the sulfuric acid catalyzed esterification of palmitic acid with isobutyl alcohol has been studied and reviewed critically. A theoretical rate equation is derived by the following reaction mechanism: (1) The reaction of sulfuric acid and isobutyl alcohol produces isobutyl sulfuric acid which acts as a catalyst; (2) Palmitic acid is protonated by the catalyst to form the reaction intermediate; and (3) The esterification proceeds reversibily. The experimental results are consistent with this rate equation.
引用
收藏
页码：17 / 26
页数：10
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