INFLUENCES OF THE SURFACE MODIFICATION OF CARBON SUPPORTS ON THE NICKEL-CATALYZED VAPOR-PHASE CARBONYLATION OF METHANOL

被引：9
|
作者：
BISCHOFF, S
MANECK, HE
PREISS, H
FUJIMOTO, K
机构：
[1] UNIV TOKYO, FAC ENGN, BUNKYO KU, TOKYO 113, JAPAN
[2] CENT INST ORGAN CHEM, O-1199 BERLIN, GERMANY
[3] CENT INST PHYS CHEM, O-1199 BERLIN, GERMANY
来源：
APPLIED CATALYSIS | 1991年 / 75卷 / 01期
关键词：
CARBON SUPPORTS; CATALYST CHARACTERIZATION (ADSORPTION; TPR; XPS; XRD); METHANOL CARBONYLATION; NICKEL CARBON;
D O I：
10.1016/S0166-9834(00)83122-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The suitability of various carbonaceous materials, modified by oxidation and/or defunctionalization in the vapor phase methanol carbonylation, was inquired. In addition to a comparison of activities and their dependence on process time, the catalysts were characterized by carbon monoxide and methyl iodide chemisorption as well as by temperature programmed reaction, XRD and XPS. While oxidized and subsequently defunctionalized carbon-supported catalysts achieved good performances, surface-oxidized carbons have been shown to be unsuitable carriers.
引用
收藏
页码：45 / 56
页数：12
相关论文
共 50 条
  • [41] Sensitive "capillary ELISA" via vapor-phase surface modification
    Kim, Wan-Joong
    Hyun, Seok Hwan
    Cho, Hyo Young
    Byun, Sangwon
    Kim, Bong Kyu
    Huh, Chul
    Chung, Kwang Hyo
    Kim, Young Jun
    SENSORS AND ACTUATORS B-CHEMICAL, 2016, 233 : 281 - 288
  • [42] Tribological properties of carbon nanopearls synthesized by nickel-catalyzed chemical vapor deposition
    Hunter, C. N.
    Check, M. H.
    Hager, C. H.
    Voevodin, A. A.
    TRIBOLOGY LETTERS, 2008, 30 (03) : 169 - 176
  • [43] Tribological Properties of Carbon Nanopearls Synthesized by Nickel-Catalyzed Chemical Vapor Deposition
    C. N. Hunter
    M. H. Check
    C. H. Hager
    A. A. Voevodin
    Tribology Letters, 2008, 30 : 169 - 176
  • [44] NICKEL-CATALYZED CARBONYLATION OF ALPHA-KETO ALKYNES UNDER PHASE-TRANSFER CONDITIONS
    ARZOUMANIAN, H
    JEAN, M
    NUEL, D
    CABRERA, A
    GUTIERREZ, JLG
    ROSAS, N
    ORGANOMETALLICS, 1995, 14 (11) : 5438 - 5441
  • [45] VAPOR-PHASE CARBONYLATION OF METHANOL OR DIMETHYL ETHER WITH METAL-ION EXCHANGED HETEROPOLY ACID CATALYSTS
    WEGMAN, RW
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (08) : 947 - 948
  • [46] A novel NiCl2-CuCl2/HMOR catalyst for direct vapor-phase carbonylation of methanol
    Wang, Hai Xia
    Guo, Wen Wen
    Zhu, Ling Jun
    ENERGY ENGINEERING AND ENVIRONMENTAL ENGINEERING, PTS 1AND 2, 2013, 316-317 : 983 - 986
  • [47] Direct vapor-phase carbonylation of methanol at atmospheric pressure on activated carbon-supported NiCl2-CuCl2 catalysts
    Peng, F
    Fu, XB
    CATALYSIS TODAY, 2004, 93-5 : 451 - 455
  • [48] Influences of Different Active Carbons on the Catalytic Performance of Ni/C Catalysts for Vapor-Phase Carbonylation of Ethanol
    Zhang Qing
    Wang Huifang
    Sun Guosong
    Huang Kelin
    Fang Weiping
    Yang Yiquan
    CHINESE JOURNAL OF CATALYSIS, 2009, 30 (06) : 555 - 559
  • [49] Redox cycle of metal-on-active carbon catalyst in the vapor phase carbonylation of methanol
    Yagita, Hiroshi, 1600, (69):
  • [50] VAPOR-PHASE SYNTHESIS OF METHYL ETHERS OF DIHYDRIC PHENOLS AND NAPHTHOLS WITH METHANOL CATALYZED BY KAOLIN
    MATSUZAKI, T
    OHSUGA, K
    SUGI, Y
    TAKAMI, Y
    IMAMURA, J
    NIPPON KAGAKU KAISHI, 1985, (12) : 2331 - 2334
12345