INFLUENCES OF THE SURFACE MODIFICATION OF CARBON SUPPORTS ON THE NICKEL-CATALYZED VAPOR-PHASE CARBONYLATION OF METHANOL

被引：9
|
作者：
BISCHOFF, S
MANECK, HE
PREISS, H
FUJIMOTO, K
机构：
[1] UNIV TOKYO, FAC ENGN, BUNKYO KU, TOKYO 113, JAPAN
[2] CENT INST ORGAN CHEM, O-1199 BERLIN, GERMANY
[3] CENT INST PHYS CHEM, O-1199 BERLIN, GERMANY
来源：
APPLIED CATALYSIS | 1991年 / 75卷 / 01期
关键词：
CARBON SUPPORTS; CATALYST CHARACTERIZATION (ADSORPTION; TPR; XPS; XRD); METHANOL CARBONYLATION; NICKEL CARBON;
D O I：
10.1016/S0166-9834(00)83122-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The suitability of various carbonaceous materials, modified by oxidation and/or defunctionalization in the vapor phase methanol carbonylation, was inquired. In addition to a comparison of activities and their dependence on process time, the catalysts were characterized by carbon monoxide and methyl iodide chemisorption as well as by temperature programmed reaction, XRD and XPS. While oxidized and subsequently defunctionalized carbon-supported catalysts achieved good performances, surface-oxidized carbons have been shown to be unsuitable carriers.
引用
收藏
页码：45 / 56
页数：12
相关论文
共 50 条
  • [21] PHASE-TRANSFER CATALYSIS IN NICKEL-CATALYZED CARBONYLATION OF ALLYL CHLORIDES
    FOA, M
    CASSAR, L
    GAZZETTA CHIMICA ITALIANA, 1979, 109 (12): : 619 - 621
  • [22] Nickel-catalyzed carbonylation of α-keto alkynes under phase transfer conditions
    Organometallics, 11 (5438):
  • [23] Deactivation and regeneration of an activated carbon-supported nickel catalyst for methanol carbonylation in the vapor phase
    Yao, Suling
    Yang, Caihong
    Tan, Yisheng
    Han, Yizhuo
    CATALYSIS COMMUNICATIONS, 2008, 9 (11-12) : 2107 - 2111
  • [24] Vapor-Phase carbonylation of organic compounds over supported transition-metal catalyst. 6. On the character of nickel/active carbon as methanol carbonylation catalyst
    Omata, Kohji
    Fujimoto, Kaoru
    Shikada, Tsutomu
    Tominaga, Hiro-o
    Industrial and Engineering Chemistry Research, 1988, 27 (12): : 2211 - 2213
  • [25] VAPOR-PHASE CARBONYLATION OF METHYL ACETATE, METHANOL, AND DIMETHYL ETHER WITH MOLYBDENUM-ACTIVE CARBON CATALYST
    SHIKADA, T
    YAGITA, H
    FUJIMOTO, K
    TOMINAGA, H
    CHEMISTRY LETTERS, 1985, (04) : 547 - 550
  • [26] Vapor-Phase Carbonylation of Methanol with the Obtaining of Acetyls on Solid-Phase Catalysts: A Review
    Kapran, A. Y.
    Pyatnitsky, Y. I.
    Chedryk, V. I.
    Orlyk, S. M.
    THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2024, 60 (02) : 77 - 90
  • [27] Synthesis of single-crystalline tungsten nanowires by nickel-catalyzed vapor-phase method at 850°C
    Wang, Shillang
    He, Yuehul
    Zou, Jin
    Jiang, Yao
    Xu, Han
    Huang, Baiyun
    Liu, C. T.
    Liaw, P. K.
    JOURNAL OF CRYSTAL GROWTH, 2007, 306 (02) : 433 - 436
  • [28] Vapor-phase surface modification of submicron particles
    Kim, YE
    Kim, SG
    Shin, HJ
    Ko, SY
    Lee, SH
    POWDER TECHNOLOGY, 2004, 139 (01) : 81 - 88
  • [29] VAPOR-PHASE CARBONYLATION OF ORGANIC-COMPOUNDS OVER SUPPORTED TRANSITION-METAL CATALYST .6. ON THE CHARACTER OF NICKEL ACTIVE-CARBON AS METHANOL CARBONYLATION CATALYST
    OMATA, K
    FUJIMOTO, K
    SHIKADA, T
    TOMINAGA, H
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1988, 27 (12) : 2211 - 2213
  • [30] Prediction of effective additives to a Ni/active carbon catalyst for vapor-phase carbonylation of methanol by an artificial neural network
    Omata, K
    Yamada, M
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (20) : 6622 - 6625
12345