INFLUENCES OF THE SURFACE MODIFICATION OF CARBON SUPPORTS ON THE NICKEL-CATALYZED VAPOR-PHASE CARBONYLATION OF METHANOL

被引：9
|
作者：
BISCHOFF, S
MANECK, HE
PREISS, H
FUJIMOTO, K
机构：
[1] UNIV TOKYO, FAC ENGN, BUNKYO KU, TOKYO 113, JAPAN
[2] CENT INST ORGAN CHEM, O-1199 BERLIN, GERMANY
[3] CENT INST PHYS CHEM, O-1199 BERLIN, GERMANY
来源：
APPLIED CATALYSIS | 1991年 / 75卷 / 01期
关键词：
CARBON SUPPORTS; CATALYST CHARACTERIZATION (ADSORPTION; TPR; XPS; XRD); METHANOL CARBONYLATION; NICKEL CARBON;
D O I：
10.1016/S0166-9834(00)83122-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The suitability of various carbonaceous materials, modified by oxidation and/or defunctionalization in the vapor phase methanol carbonylation, was inquired. In addition to a comparison of activities and their dependence on process time, the catalysts were characterized by carbon monoxide and methyl iodide chemisorption as well as by temperature programmed reaction, XRD and XPS. While oxidized and subsequently defunctionalized carbon-supported catalysts achieved good performances, surface-oxidized carbons have been shown to be unsuitable carriers.
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页码：45 / 56
页数：12
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