Crystal structure of [(2S,3R)-3-hydroxy-phenylbutan-2-yl]pyrrolidinium chloride

被引：0
|
作者：
Kandhaswamy, Abirami [1 ]
Meena, K. S. [1 ]
Deepa, S. [2 ]
Murugavel, S. [3 ]
机构：
[1] Queen Marys Coll, Dept Chem, Madras 600004, Tamil Nadu, India
[2] Govt Coll Engn, Dept Phys, Salem 636011, India
[3] Thanthai Periyar Govt Inst Technol, Dept Phys, Vellore 632002, Tamil Nadu, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; salt; pyrrolidinium chloride; ionic liquids; hydrogen bonding;
D O I：
10.1107/S2056989015016916
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title molecular salt, C14H22NO+center dot Cl-, the pyrrolidinium ring adopts a twisted conformation about one of the N-C bonds. It is oriented at a dihedral angle of 42.0 (1)degrees with respect to the benzene ring. The torsion angle for the central N-C-C-Car (ar = aromatic) linkage is 163.74 (15)degrees. In the crystal, the components are linked via N -H" " "Cl and O-H center dot center dot center dot Cl" hydrogen bonds, forming zigzig chains along the b -axis direction. These chains are connected along the c axis by very weak C-H center dot center dot center dot pi interactions, forming a two-dimensional supramolecular network.
引用
收藏
页码：O758 / U411
页数：8
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