Crystal structure of [(2S,3R)-3-hydroxy-phenylbutan-2-yl]pyrrolidinium chloride

被引：0
|
作者：
Kandhaswamy, Abirami [1 ]
Meena, K. S. [1 ]
Deepa, S. [2 ]
Murugavel, S. [3 ]
机构：
[1] Queen Marys Coll, Dept Chem, Madras 600004, Tamil Nadu, India
[2] Govt Coll Engn, Dept Phys, Salem 636011, India
[3] Thanthai Periyar Govt Inst Technol, Dept Phys, Vellore 632002, Tamil Nadu, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; salt; pyrrolidinium chloride; ionic liquids; hydrogen bonding;
D O I：
10.1107/S2056989015016916
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title molecular salt, C14H22NO+center dot Cl-, the pyrrolidinium ring adopts a twisted conformation about one of the N-C bonds. It is oriented at a dihedral angle of 42.0 (1)degrees with respect to the benzene ring. The torsion angle for the central N-C-C-Car (ar = aromatic) linkage is 163.74 (15)degrees. In the crystal, the components are linked via N -H" " "Cl and O-H center dot center dot center dot Cl" hydrogen bonds, forming zigzig chains along the b -axis direction. These chains are connected along the c axis by very weak C-H center dot center dot center dot pi interactions, forming a two-dimensional supramolecular network.
引用
收藏
页码：O758 / U411
页数：8
相关论文
共 50 条
  • [41] SYNTHESIS OF (2S,3R)-3-HYDROXYLEUCINE - A CONSTITUENT OF LYSOBACTIN
    YADAV, JS
    CHANDRASEKHAR, S
    REDDY, YR
    RAO, AVR
    TETRAHEDRON, 1995, 51 (09) : 2749 - 2754
  • [42] Synthesis of poly[isobutyl (2S,3R)-3-benzyloxyaspartate]
    GarciaMartin, MD
    dePaz, MV
    Galbis, JA
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1997, 198 (01) : 219 - 227
  • [43] Asymmetric synthesis of (2S,3S)- and (2S,3R)-3-prolinomethionines: 3-methylsulfanylmethyl-pyrrolidine-2-carboxylic acids
    Karoyan, P
    Chassaing, G
    TETRAHEDRON-ASYMMETRY, 1997, 8 (12) : 2025 - 2032
  • [44] SYNTHESIS OF (3R)-3-HYDROXY-2-HEXANONE, (2R,3R)-2,3-HEXANEDIOL AND (2S,3R)-2,3-HEXANEDIOL, THE MALE SEX-PHEROMONE OF HYLOTRUPES-BAJULUS AND PYRRHIDIUM-SANGUINEUM (CERAMBYCIDAE)
    SCHRODER, F
    FETTKOTHER, R
    NOLDT, U
    DETTNER, K
    KONIG, WA
    FRANCKE, W
    LIEBIGS ANNALEN DER CHEMIE, 1994, (12): : 1211 - 1218
  • [45] Assymetric synthesis of (2S,3R)- and (2S,3S)-[2-13C;3-2H] glutamic acid
    Okuma, Kosuke
    Ono, Akira M.
    Tsuchiya, Seiji
    Oba, Makoto
    Nishiyama, Kozaburo
    Kainosho, Masatsune
    Terauchi, Tsutomu
    TETRAHEDRON LETTERS, 2009, 50 (13) : 1482 - 1484
  • [46] Stereoselective synthesis of (1R,2S,3R)-camphordiamine
    Busacca, CA
    Campbell, S
    Dong, Y
    Grossbach, D
    Ridges, M
    Smith, L
    Spinelli, E
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (15): : 4753 - 4755
  • [47] SYNTHESES OF (2S,3R)-3-METHYLASPARTIC AND (2S,3R)[3-H-2]-3-METHYLASPARTIC ACIDS - SLOW SUBSTRATES FOR A SYN-ELIMINATION REACTION CATALYZED BY METHYLASPARTASE
    ARCHER, CH
    THOMAS, NR
    GANI, D
    TETRAHEDRON-ASYMMETRY, 1993, 4 (06) : 1141 - 1152
  • [48] SYNTHESIS OF (2S,3S)-[3-2H1]-PROLINE AND (2S,3R)-[2,3-2H2]-PROLINE
    DIETERICH, P
    YOUNG, DW
    TETRAHEDRON LETTERS, 1993, 34 (34) : 5455 - 5458
  • [49] VERSATILE SYNTHESIS OF STEREOSPECIFICALLY LABELED D-AMINO ACIDS VIA LABELED AZIRIDINES - PREPARATION OF (2R,3S)-[3-H-2(1)]-SERINE AND (2R,3R)-[2,3-H-2(2)]-SERINE (2S,2'S,3S,3'S-[3,3'-H-2(2)]-CYSTINE AND (2S,2'S,3R,3'R)-[2,2',3,3'-H-2(4)]-CYSTINE AND (2S,3S)-[3-H-2(1)-] AND (2S,3R)-[2,3-H-2(2)]-BETA-CHLOROALANINE
    AXELSSON, BS
    OTOOLE, KJ
    SPENCER, PA
    YOUNG, DW
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (07): : 807 - 815
  • [50] Crystal structure of (2S*,3R*)-N-benzyl-2-(benzyloxy)-3-(hydroxylamino)pentane, C19H25NO2
    Merino, P
    Castillo, E
    Merchan, FL
    Tejero, T
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1997, 212 (03): : 443 - 444
12345