ASYMMETRIC-SYNTHESIS OF THE AB-RING OF AKLAVINONE

被引：10

作者：

DAVIS, FA

KUMAR, A

机构：

[1] Department of Chemistry, Drexel University, Philadelphia

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 52期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(91)80561-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A formal synthesis of the AB-ring of aklavinone 3 was achieved via the asymmetric synthesis of diol 8 prepared in three steps from tetralone 5. The crucial step involved the asymmetric hydroxylation of 5 in greater-than-or-equal-to 95% ee using (camphorylsulfonyl)oxaziridine derivative (+)-4b.

引用

页码：7671 / 7674

页数：4

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