1,3-DIPHENYLCYCLOPENTADIENYL COMPLEXES OF SODIUM, INDIUM(I), THALLIUM(I) AND IRON(II) - X-RAY STRUCTURAL-ANALYSIS OF TL(C(5)H(3)PH(2))(THF) AND FE(C(5)H(3)PH(2))(2)

被引：25

作者：

SCHUMANN, H

LENTZ, A

WEIMANN, R

机构：

[1] Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin, Straße des, 17. Juni 135

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

DIPHENYLCYCLOPENTADIENE; SODIUM; INDIUM; THALLIUM; IRON;

D O I：

10.1016/0022-328X(94)05098-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,4-Diphenylcyclopentadiene (1) reacts with TlOC2H5 or NaNH2 to give the corresponding half-sandwich complexes Na(C(5)H(3)Ph(2)) (2) and Tl(C(5)H(3)Ph(2)) (4). 2 reacts with InCl to form In(C(5)H(3)Ph(2)) (3), and 2 as well as 4 react with FeCl2 to form Fe(C(5)H(3)Ph(2))(2) (5). The H-1, C-13 NMR and mass spectra of the new compounds, as well as the X-ray crystal structure analyses of 4 and 5, are reported and discussed.

引用

页码：245 / 252

页数：8

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