Synthesis and structure of bismuth-containing complexes [(Ph4BiO)2{2,5-(CH3)2C6H3S(O)}2+ [Ph2Bi2I6]2,[(Ph4Bi]+[PhBi(C5H5N)I3]–, [Ph4Sb[Bi4I16]4·2(CH3)2 C=O, and [Ph4Sb3+[Bi5I18]3–

被引：0
|
作者：
V. V. Sharutin
I. V. Egorova
O. K. Sharutina
O. A. Dorofeeva
T. K. Ivanenko
A. V. Gerasimenko
M. A. Pushilin
机构：
[1] Blagoveshchensk State Pedagogical University,Institute of Chemistry, Far East Division
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2004年 / 30卷
关键词：
Physical Chemistry; Acetone; Inorganic Chemistry; Bismuth; C5H5N;
D O I：
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中图分类号：
学科分类号：
摘要：
The reactions of tetraphenylbismuthonium and -stibonium salts Ph4EX (E = Bi, Sb; X = I, OSO2 (C6H3(CH3)2-2,5), OSO2C6H3(OH-4)(COOH-3)) with bismuth triiodide in acetone afford complexes [Ph4Bi]+[PhBi(C5H5N)I3]-, [(Ph4BiO)2S(O){2,5-(CH3)2C6H3S(O)} [Ph2Bi2I6]2–, [Ph4Sb [Bi4I16]4-·2(CH3)2C=O, and [Ph4Sb]3++ [Bi5I18]3-, whose structural units, according to the X-ray diffraction data, are tetraphenylbismuthonium (-stibonium) cations and mono-, di-, tetra-, and pentanuclear anions, respectively.
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页码：874 / 883
页数：9
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