Synthesis and structure of [(μ4-succinato)hexadecaphenyltetraantimony] triiodide solvate with benzene [(Ph4Sb)2O2CCH2CH2CO2(Ph4Sb)2][I3]2 · 4PhH

被引：0
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作者：
V. V. Sharutin
O. K. Sharutina
Yu. O. Gubanova
P. V. Andreev
N. V. Somov
机构：
[1] National Research South Ural State University,
[2] Nizhny Novgorod State University,undefined
来源：
Russian Journal of Coordination Chemistry | 2017年 / 43卷
关键词：
bis(tetraphenylantimony) succinate; interaction; iodine; benzene;
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摘要：
The reaction of bis(tetraphenylantimony) succinate with iodine in benzene affords [(μ4-succinato) hexadecaphenyltetraantimony] triiodide solvate with benzene [(Ph4Sb)2O2CCH2CH2-CO2(Ph4Sb)2][I3]2 · 4PhH (I). The symmetrically nonequivalent Sb(1) and Sb(2) atoms in the centrosymmetric cation of compound I have a distorted trigonal bipyramidal coordination mode with the oxygen atoms in the axial positions (Sb(1,2)−O 2.347(4) 2.525(4) Å; Sb(1,2)−Cequiv 2.109(7)−2.120(7) Å, 2.082(5)−2.106(7) Å; Sb(1,2)−Caxial 2.158(7), 2.121(9) Å; angles OSb(1,2)C 178.8(2)°, 174.5(3)°). The geometry of the [I3]− anions is close to linear (angle III 179.41(4)°, I−I distances 2.880(1) and 2.921(1) Å) (CIF file CCDC no. 1486690).
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页码：453 / 456
页数：3
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