Trichlorido(5,5'-dimethyl-2,2'-bipyridine-kappa N-2,N')(dimethylformamide-kappa O)-indium(III) hemihydrate

被引：2
|
作者：
Shirvan, Sadif A. [1 ]
Dezfuli, Sara Haydari [1 ]
Khazali, Fereydoon [1 ]
Aghajeri, Manouchehr [1 ]
Borsalani, Ali [2 ]
机构：
[1] Islamic Azad Univ, Dept Chem, Omidieh Branch, Omidieh, Iran
[2] Islamic Azad Univ, Dept Petr Engn, Omidieh Branch, Omidieh, Iran
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 17.2; mean ω(C-C) = 0.005 Å; R factor = 0.034; single-crystal X-ray study; T = 173 K; wR factor = 0.067;
D O I：
10.1107/S1600536812044698
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]center dot 0.5H(2)O, contains two independent In III complex molecules with similar structures and one lattice water molecule. In each complex molecule, the In III atom is six-coordinated in a distorted octahedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethylformamide and three facial Cl atoms. In the crystal, the lattice water molecule is linked to the complex molecules via O-H center dot center dot center dot Cl hydrogen bonds. Further weak C-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen bonds result in the formation of a three-dimensional structure.
引用
收藏
页码：M1448 / +
页数：13
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