Trichlorido(5,5'-dimethyl-2,2'-bipyridine-kappa N-2,N')(dimethylformamide-kappa O)-indium(III) hemihydrate

被引：2

作者：

Shirvan, Sadif A. ^{[1
]}

Dezfuli, Sara Haydari ^{[1
]}

Khazali, Fereydoon ^{[1
]}

Aghajeri, Manouchehr ^{[1
]}

Borsalani, Ali ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Omidieh Branch, Omidieh, Iran

[2] Islamic Azad Univ, Dept Petr Engn, Omidieh Branch, Omidieh, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 17.2; mean ω(C-C) = 0.005 Å; R factor = 0.034; single-crystal X-ray study; T = 173 K; wR factor = 0.067;

D O I：

10.1107/S1600536812044698

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]center dot 0.5H(2)O, contains two independent In III complex molecules with similar structures and one lattice water molecule. In each complex molecule, the In III atom is six-coordinated in a distorted octahedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethylformamide and three facial Cl atoms. In the crystal, the lattice water molecule is linked to the complex molecules via O-H center dot center dot center dot Cl hydrogen bonds. Further weak C-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen bonds result in the formation of a three-dimensional structure.

引用

页码：M1448 / +

页数：13

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