ON A NEW COPPER-TIN BORATE OXIDE WITH ISOLATED BO3 UNITS - CU5SN(BO3)2O4

被引：19
|
作者：
SCHAEFER, J [1 ]
BLUHM, K [1 ]
机构：
[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,D-24118 KIEL,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 09期
关键词：
COPPER; TIN; BORATE; OXIDE; SYNTHESIS; CRYSTAL STRUCTURE; X-RAY DIFFRACTION;
D O I：
10.1002/zaac.19946200914
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single Crystals of the new compound Cu5Sn(BO3)2O4 were obtained by a B2O3 fluxtechnique. They crystallize in a monoclinic distorted variant of a Ludwigite structure with a partly ordered metal distribution. X-ray investigations on single crystals led to the space group C2h5-P2(1)/c (No. 14); a = 6.3526(7); b = 9.502(1); c = 12.100(9) angstrom; beta = 93.30(3)-degree; Z = 4. All metal-sites are distorted octahedraly coordinated by oxygen-ions. The structure contains BO3-units and oxygen which is not coordinated to boron.
引用
收藏
页码：1578 / 1582
页数：5
相关论文
共 50 条
  • [31] Experimental and ab initio studies of Cd5(BO3)3Cl: the first cadmium borate chlorine NLO material with isolated BO3 groups
    Song, Yunxia
    Luo, Min
    Liang, Fei
    Lin, Chensheng
    Ye, Ning
    Yan, Guiyang
    Lin, Zheshuai
    DALTON TRANSACTIONS, 2017, 46 (44) : 15228 - 15234
  • [32] X-RAY DATA AND SPATIAL GROUP OF PR2SR3(BO3)4,GD2SR3(BO3)4,LA2BA3(BO3)4,LA2SR3(BO3)4 MIXED BORATES
    PALKINA, KK
    KUZNETSO.VG
    MORUGA, LG
    DZHURINS.BF
    ZHURNAL NEORGANICHESKOI KHIMII, 1972, 17 (03): : 652 - &
  • [33] SYNTHESIS AND CRYSTAL-STRUCTURE OF MANGANESE BORATE OXIDES - MNFE(BO3)O AND MNAL0.5Y0.5(BO3)O
    UTZOLINO, A
    BLUHM, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (08): : 1146 - 1150
  • [34] Stoichiometric, trigonal huntite borate CeSc3(BO3)4
    Peterson, GA
    Keszler, DA
    Reynolds, TA
    INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2000, 2 (01): : 101 - 106
  • [35] A new sodium samarium borate Na3Sm2(BO3)3
    Zhang, GC
    Wu, YC
    Fu, PZ
    Wang, GF
    Liu, HJ
    Fan, G
    Chen, CT
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2002, 63 (01) : 145 - 149
  • [36] Structure of two new borates YCa3(A1O)3(BO3)4 and YCa3(GaO)3(BO3)4
    Yu, Y
    Wu, QS
    Li, RK
    JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (02) : 429 - 432
  • [37] Synthesis, growth and some physical properties of new orthoborates ScBaNa(BO3)2 and YBaNa(BO3)2
    Svetlyakova, T.
    Kononova, N.
    Kokh, A.
    Urakaev, F.
    Filatov, S.
    Bubnova, R.
    Kokh, K.
    JOURNAL OF CRYSTAL GROWTH, 2011, 318 (01) : 954 - 957
  • [38] Li3La2(BO3)3 and Li1.75Na1.25La2(BO3)3: A Great Enhancement in Birefringence Induced by Optimal Arrangement of π-Conjugated [BO3] Units
    Shi, Xuping
    Zhang, Wenbin
    Cai, Wenbing
    Han, Shujuan
    Yang, Zhihua
    Pan, Shilie
    INORGANIC CHEMISTRY, 2021, 60 (16) : 12565 - 12572
  • [39] Lead zinc borate, PbZn2(BO3)2
    Chen, XA
    Zhao, YH
    Chang, XA
    Zhang, L
    Xue, HP
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2006, 62 : I11 - I12
  • [40] Lattice dynamics and electronic transitions in a structurally complex layered copper borate Cu3(BO3)2
    Molchanova, A. D.
    Prosnikov, M. A.
    Dubrovin, R. M.
    Davydov, V. Yu.
    Smirnov, A. N.
    Pisarev, R. V.
    Boldyrev, K. N.
    Popova, M. N.
    PHYSICAL REVIEW B, 2017, 96 (17)
12345