ON A NEW COPPER-TIN BORATE OXIDE WITH ISOLATED BO3 UNITS - CU5SN(BO3)2O4

被引：19
|
作者：
SCHAEFER, J [1 ]
BLUHM, K [1 ]
机构：
[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,D-24118 KIEL,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 09期
关键词：
COPPER; TIN; BORATE; OXIDE; SYNTHESIS; CRYSTAL STRUCTURE; X-RAY DIFFRACTION;
D O I：
10.1002/zaac.19946200914
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single Crystals of the new compound Cu5Sn(BO3)2O4 were obtained by a B2O3 fluxtechnique. They crystallize in a monoclinic distorted variant of a Ludwigite structure with a partly ordered metal distribution. X-ray investigations on single crystals led to the space group C2h5-P2(1)/c (No. 14); a = 6.3526(7); b = 9.502(1); c = 12.100(9) angstrom; beta = 93.30(3)-degree; Z = 4. All metal-sites are distorted octahedraly coordinated by oxygen-ions. The structure contains BO3-units and oxygen which is not coordinated to boron.
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收藏
页码：1578 / 1582
页数：5
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