1,3-BUTADIENYLTRIBUTYLPHOSPHONIUM BROMIDE AS A CONJUNCTIVE REAGENT FOR THE SYNTHESIS OF 1,3-DIENES FROM CARBONYL-COMPOUNDS AND GILMAN CUPRATES

被引：1

作者：

SCHEUPLEIN, SW ^{[1
]}

BRUCKNER, R ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,W-3550 MARBURG,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 08期

关键词：

CONJUGATE ADDITION; CUPRATES; 1,3-DIENES; WITTIG REACTION;

D O I：

10.1002/cber.19911240827

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot non-stereoselective synthesis of 1,3-dienes from (4-bromo-2-butenyl)tributylphosphonium bromide (9), Gilman cuprates, and aldehydes or ketones is described. The yields of the dienes reach 79% or 63% when aldehydes and ketones are used, respectively. The pentadienylsilane 10k is accessible similarly in 56% yield.

引用

页码：1871 / 1874

页数：4

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