THE HYDROXYLATION OF GLOBULOL AND 7-EPIGLOBULOL BY CEPHALOSPORIUM-APHIDICOLA

被引：14
|
作者：
HANSON, JR
HITCHCOCK, PB
MANICKAVASAGAR, R
机构：
[1] School of Molecular Sciences, University of Sussex, Brighton
来源：
PHYTOCHEMISTRY | 1994年 / 37卷 / 04期
关键词：
CEPHALOSPORIUM APHIDICOLA; GLOBULOL; 7-EPIGLOBULOL; SESQUITERPENOID; MICROBIOLOGICAL HYDROXYLATION;
D O I：
10.1016/S0031-9422(00)89521-7
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Globulol and 7-epiglobulol were shown to be hydroxylated by Cephalosporium aphidicola on one (C-14) of the methyl groups geminal to the cyclopropane ring in 48.5 and 56% yield, respectively. The significance of this hydroxylation adjacent to a cyclopropane ring is noted.
引用
收藏
页码：1023 / 1025
页数：3
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    HANSON, JR
    IQBAL, Z
    [J]. PHYTOCHEMISTRY, 1994, 37 (03) : 723 - 726
  • [2] MICROBIOLOGICAL HYDROXYLATION OF SOME ADAMANTANE DERIVATIVES BY CEPHALOSPORIUM-APHIDICOLA
    FAROOQ, A
    HANSON, JR
    [J]. JOURNAL OF CHEMICAL RESEARCH-S, 1995, (04): : 150 - 151
  • [3] THE MICROBIOLOGICAL HYDROXYLATION OF SOME PINANE MONOTERPENOIDS BY CEPHALOSPORIUM-APHIDICOLA
    FAROOQ, A
    HANSON, JR
    [J]. PHYTOCHEMISTRY, 1995, 40 (03) : 815 - 817
  • [4] THE BIOTRANSFORMATION OF CYCLODODECANONE BY CEPHALOSPORIUM-APHIDICOLA
    HANSON, JR
    PARVEZ, A
    [J]. JOURNAL OF CHEMICAL RESEARCH-S, 1995, (08): : 332 - 333
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    HANSON, JR
    HITCHCOCK, PB
    JARVIS, AG
    RODRIGUEZPEREZ, EM
    RATCLIFFE, AH
    [J]. PHYTOCHEMISTRY, 1992, 31 (03) : 799 - 803
  • [6] BIOTRANSFORMATION OF THE SESQUITERPENOID, CEDROL, BY CEPHALOSPORIUM-APHIDICOLA
    HANSON, JR
    NASIR, H
    [J]. PHYTOCHEMISTRY, 1993, 33 (04) : 835 - 837
  • [7] THE BIOTRANSFORMATION OF SOME STEROIDS BY CEPHALOSPORIUM-APHIDICOLA
    HANSON, JR
    NASIR, H
    [J]. PHYTOCHEMISTRY, 1993, 33 (04) : 831 - 834
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    HANSON, JR
    HITCHCOCK, PB
    NASIR, H
    TRUNEH, A
    [J]. PHYTOCHEMISTRY, 1994, 36 (04) : 903 - 906
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    HANSON, JR
    JARVIS, AG
    RATCLIFFE, AH
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    REESE, PB
    TAKAHASHI, JA
    WILSON, MR
    [J]. PHYTOCHEMISTRY, 1994, 36 (06) : 1391 - 1393
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