THE HYDROXYLATION OF GLOBULOL AND 7-EPIGLOBULOL BY CEPHALOSPORIUM-APHIDICOLA

被引：14
|
作者：
HANSON, JR
HITCHCOCK, PB
MANICKAVASAGAR, R
机构：
[1] School of Molecular Sciences, University of Sussex, Brighton
来源：
PHYTOCHEMISTRY | 1994年 / 37卷 / 04期
关键词：
CEPHALOSPORIUM APHIDICOLA; GLOBULOL; 7-EPIGLOBULOL; SESQUITERPENOID; MICROBIOLOGICAL HYDROXYLATION;
D O I：
10.1016/S0031-9422(00)89521-7
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Globulol and 7-epiglobulol were shown to be hydroxylated by Cephalosporium aphidicola on one (C-14) of the methyl groups geminal to the cyclopropane ring in 48.5 and 56% yield, respectively. The significance of this hydroxylation adjacent to a cyclopropane ring is noted.
引用
收藏
页码：1023 / 1025
页数：3
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