Catalysis with TS-1: New perspectives for the industrial use of hydrogen peroxide

被引：0
|
作者：
Ingallina, P
Clerici, MG
Rossi, L
Bellussi, G
机构：
来源：
SCIENCE AND TECHNOLOGY IN CATALYSIS 1994 | 1995年 / 92卷
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
TS-1 modified with Pd or Pt is an active catalyst in the oxidation of alkanes by means of H-2 and O-2. In the case of hexane, the corresponding internal alcohols and ketones are produced with selectivities on O-2 ranging between 10 and 20%. Analogously, TS-1 is an active catalyst in the oxidation of organic substrates by means of H-2 and O-2 provided that a redox couple, such as anthraquinone/anthrahydroquinone, is also present. In the case of propylene, the corresponding oxide is produced with 78% yield.
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页码：31 / 39
页数：9
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