Catalysis with TS-1: New perspectives for the industrial use of hydrogen peroxide

被引：0
|
作者：
Ingallina, P
Clerici, MG
Rossi, L
Bellussi, G
机构：
来源：
SCIENCE AND TECHNOLOGY IN CATALYSIS 1994 | 1995年 / 92卷
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
TS-1 modified with Pd or Pt is an active catalyst in the oxidation of alkanes by means of H-2 and O-2. In the case of hexane, the corresponding internal alcohols and ketones are produced with selectivities on O-2 ranging between 10 and 20%. Analogously, TS-1 is an active catalyst in the oxidation of organic substrates by means of H-2 and O-2 provided that a redox couple, such as anthraquinone/anthrahydroquinone, is also present. In the case of propylene, the corresponding oxide is produced with 78% yield.
引用
收藏
页码：31 / 39
页数：9
相关论文
共 50 条
  • [31] Decomposition of hydrogen peroxide in protic and polar aprotic solvents on TS-1 heterogeneous catalyst
    Potekhin, V. V.
    Kulikova, V. A.
    Kochina, E. G.
    Potekhin, V. M.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (07) : 1195 - 1200
  • [32] Epoxidation of Propylene with Hydrogen Peroxide Over TS-1 Catalyst Synthesized in the Presence of Polystyrene
    Sunyoung Park
    Kyung Min Cho
    Min Hye Youn
    Jeong Gil Seo
    Sung-Hyeon Baeck
    Tae Jin Kim
    Young-Min Chung
    Seung-Hoon Oh
    In Kyu Song
    Catalysis Letters, 2008, 122 : 349 - 353
  • [33] Catalytic activity of TS-1 on the hydroxylation of benzene and toluene with hydrogen peroxide in a bubble reactor
    Sakullimcharoen, Suchitraporn
    Manit, Panas
    Mongkhonsi, Tharathon
    CHIANG MAI JOURNAL OF SCIENCE, 2008, 35 (01): : 163 - 170
  • [34] Influence of Pt–Pd/TS-1 Catalyst Preparation on Epoxidation of Olefins with Hydrogen Peroxide
    Qingfa Wang
    Li Wang
    Zhentao Mi
    Catalysis Letters, 2005, 103 : 161 - 164
  • [35] Technological parameters of the epoxidation of allyl alcohol with hydrogen peroxide over TS-1 and TS-2 catalysts
    Wróblewska, A
    Milchert, E
    CHEMICAL PAPERS, 2002, 56 (03) : 150 - 157
  • [36] Epoxidation of 1-hexene with hydrogen peroxide over nitrogen-incorporated TS-1 zeolite
    Li, Hao
    Xu, Bo
    Deng, Bangwei
    Yan, Xuemin
    Zheng, Yancheng
    CATALYSIS COMMUNICATIONS, 2014, 46 : 224 - 227
  • [37] Optimization of the technological parameters of epoxidation of methallyl chloride by hydrogen peroxide over TS-1 catalyst
    Wróblewska, A
    Milchert, E
    ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2006, 10 (03) : 525 - 533
  • [38] Technological parameter optimization for epoxidation of methallyl alcohol by hydrogen peroxide over TS-1 catalyst
    Wroblewska, Agnieszka
    Lawro, Ewelina
    Milchert, Eugeniusz
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (22) : 7365 - 7373
  • [39] Effect of Ti Speciation on Catalytic Performance of TS-1 in the Hydrogen Peroxide to Propylene Oxide Reaction
    Signorile, Matteo
    Crocella, Valentina
    Damin, Alessandro
    Rossi, Barbara
    Lamberti, Carlo
    Bonino, Francesca
    Bordiga, Silvia
    JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (16): : 9021 - 9034
  • [40] Direct epoxidation of propylene with hydrogen peroxide over TS-1 catalysts: Effect of hydrophobicity of the catalysts
    Park, Sunyoung
    Cho, Kyung Min
    Youn, Min Hye
    Seo, Jeong Gil
    Jung, Ji Chul
    Baeck, Sung-Hyeon
    Kim, Tae Jin
    Chung, Young-Min
    Oh, Seung-Hoon
    Song, In Kyu
    CATALYSIS COMMUNICATIONS, 2008, 9 (15) : 2485 - 2488
12345