Transfer hydrogenation of a carbonyl compound in glycerol-based solvent mixtures

被引：0
|
作者：
Wolfson, Adi [1 ]
Abu-Zaed, Hamdy [1 ]
Tavor, Dorith [1 ]
机构：
[1] Sami Shamoon Coll Engn, Green Proc Ctr, Bialik St 56, IL-84100 Beer Sheva, Israel
来源：
ORGANIC COMMUNICATIONS | 2016年 / 9卷 / 01期
关键词：
Glycerol; triacetin; green chemistry and sustainable solvent;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Three representative carbonyl compounds were efficiently hydrogenated in a glycerol-triacetin or glycerol-tributyrin mixture. The addition of triacetin to glycerol favorably altered the polarity of the reaction mixture, thereby increasing the solubility of reactants and, in turn, reactant conversion rates. Maximum conversion was detected in a glycerol-triacetin mixture (80:20) in the presence of a Ru(p-cymene)Cl-2-dimer catalyst.
引用
收藏
页码：9 / 14
页数：6
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