N-(2,6-Diisopropylphenyl)-N-{3-[(2,6-diisopropylphenyl)imino]butan-2-yl}azanide trihloridostannate(II)

被引：0

作者：

Ma, Xiaoli ^{[1
]}

Sun, Shuai ^{[1
]}

Hao, Pengfei ^{[1
]}

Yang, Ying ^{[2
]}

Yang, Zhi ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[2] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1107/S1600536812014729

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, (C28H43N2)[SnCl3], two pairs of molecular species are present in the asymmetric unit. The employed a-diimine opens up, forming a highly asymmetric ammonium that has its protons at one of the N atoms [N-C=1.264 (4) and 1.516 (4) angstrom]. One of the C=N double bonds was oxidized to C-N, which is consistent with the bond length of 1.516 (4) angstrom. Meanwhile Sn-IV was reduced to Sn-II. The (SnCl)(3)(-) anion is trigonal-pyramidal. In the crystal, molecules are linked by C-H center dot center dot center dot Cl, N-H center dot center dot center dot Cl, N-H center dot center dot center dot N and C-H center dot center dot center dot N bonds. The crystal studied was twinned by pseudo-merohedry.

引用

页码：N719 / +

页数：16

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