Synthesis and structural studies of group 2B transition metal complexes with the bulky nitrogen ligand Bis[N-(2,6-diisopropylphenyl) imino]acenaphthene

被引：7

作者：

El-Ayaan, U ^{[1
]}

机构：

[1] Mansoura Univ, Fac Sci, Dept Chem, Mansoura 35516, Egypt

来源：

MONATSHEFTE FUR CHEMIE | 2004年 / 135卷 / 08期

关键词：

N-ligands; X-ray structure determination; group 2B transition metal complexes;

D O I：

10.1007/s00706-004-0181-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Group 2B transition metal complexes of bis[N-(2,6-diisopropylphenyl)imino]acenaphthene (o,o'-iPr(2)C(6)H(3)-BIAN), namely, [Hg(o,o'-iPr(2)C(6)H(3)-BIAN)Cl-2] (1), [Zn(o,o'-iPr(2)C(6)H(3)-BIAN)(2)](ClO4)(2) (2), and [Cd(o,o'-iPr(2)C(6)H(3)-BIAN)(2)](ClO4)(2) (3) have been synthesized and characterized. In complexes 2 and 3, IR, NMR, and conductivity measurements confirm the coordination of two (o,o'-iPr(2)C(6)H(3)-BIAN) ligands to the metal center with two discrete perchlorate anions. X-Ray crystal structure of 1 indicates a distorted tetrahedral geometry with two nitrogen atoms from (o,o'-iPr(2)C(6)H(3)-BIAN) ligand and two chloride atoms coordinating to the Hg(II) center.

引用

页码：919 / 925

页数：7

共 50 条

[1] Synthesis and Structural Studies of Group 2B Transition Metal Complexes with the Bulky Nitrogen Ligand Bis[N-(2,6-diisopropylphenyl) imino]acenaphthene
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[J]. Monatshefte für Chemie / Chemical Monthly, 2004, 135 : 919 - 925
[2] Synthesis and structural studies of diamagnetic first-row transition metal complexes with the rigid nitrogen ligand:: bis[N-(2,6-diisopropylphenyl)imino]acenaphthene
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