SYNTHESIS OF A PHOSPHONATED STYRENE MONOMER - INSTABILITY OF THE DIACIDIC MOIETY AND POLYMERIZATION

被引：8
|
作者：
BOUTEVIN, B
HAMOUI, B
BESSIERE, JMM
机构：
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 1995年 / 196卷 / 06期
关键词：
D O I：
10.1002/macp.1995.021960606
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
p-vinylbenzylphosphonic acid was prepared by means of the Arbuzov reaction between triethyl phosphite and p-chloromethylstyrene followed by silylation with bromotrimethylsilane and methanolysis. The product, which is readily cross-linked, is stabilized as dicyclohexylammonium salt. Radical-initiated polymerization occurs readily; homo- and copolymers found are slowly cross-linked upon releasing dicyclohexylamine.
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页码：1865 / 1873
页数：9
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