Synthesis of Reactive Poly(norbornene): Ring-Opening Metathesis Polymerization of Norbornene Monomer Bearing Cyclic Dithiocarbonate Moiety

被引：13
|
作者：
Sudo, Atsushi [1 ]
Morishita, Hidetada [1 ]
Endo, Takeshi [1 ]
机构：
[1] Kinki Univ, Mol Engn Inst, Fukuoka 8208555, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2011年 / 49卷 / 05期
关键词：
copolymerization; functionalization of polymers; ROMP; ROMP POLYMERS; HIGH-LOAD; COPOLYMERS; RAFT;
D O I：
10.1002/pola.24523
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A norbornene monomer bearing cyclic dithiocarbonate moiety (NB-DTC) was successfully synthesized from the corresponding precursor having epoxy moiety by its reaction with carbon disulfide. NB-DTC underwent the ring-opening metathesis polymerization (ROMP) catalyzed by a ruthenium carbene complex to give the corresponding poly(norbornene). The dithiocarbonate moiety incorporated into the side chain of the obtained poly(norbornene) reacted with amine to afford the corresponding thiourethane moiety with thiol group, which underwent oxidative S-S coupling and/or addition reaction to the C-C double bond in the main chain, leading to formation of a cross-linked polymer. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 1097-1103, 2011
引用
收藏
页码：1097 / 1103
页数：7
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