Kaolin-SO3H as an efficient catalyst for one- pot synthesis of 1,2,4,5-tetrasubstituted imidazoles

被引:0
|
作者
Mirjalili, Bibi Fatemeh [1 ]
Akrami, Hamidreza [1 ]
机构
[1] Yazd Univ, Dept Chem, Coll Sci, POB 89195-741, Yazd, Iran
来源
IRANIAN JOURNAL OF CATALYSIS | 2015年 / 5卷 / 02期
关键词
1,2,4,5-tetrasubstituted imidazoles; Kaolin-SO3H; Benzil; One-pot synthesis; Solvent-free conditions;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Kaolin-SO3H as a new solid acid is prepared via reaction of kaolin and chlorosulfonic acid. This natural based catalyst is very inexpensive and easy available. A simple, highly versatile and efficient synthesis of 1,2,4,5-tetrasubstituted imidazoles is achieved using Kaolin-SO3H as a catalyst at moderate temperature under solvent-free condition. The key advantages of this process are high yields with simple work-up using easy available inexpensive natural based catalyst.
引用
下载
收藏
页码:129 / 134
页数:6
相关论文
共 50 条
  • [1] One-Pot Synthesis of 1,2,4,5-Tetrasubstituted Imidazoles in Ionic Liquid
    Wan, Yu
    Liu, Gui-xiang
    Zhao, Ling-ling
    Wang, Hai-ying
    Huang, Shu-ying
    Chen, Liang-feng
    Wu, Hui
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2014, 51 (03) : 713 - 718
  • [2] Efficient one-pot synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles using SBA-Pr-SO3H as a green nano catalyst
    Ziarani, Ghodsi Mohammadi
    Badiei, Alireza
    Lashgari, Negar
    Farahani, Zahra
    JOURNAL OF SAUDI CHEMICAL SOCIETY, 2016, 20 (04) : 419 - 427
  • [3] L-Proline: an efficient catalyst for the one-pot synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles
    Samai, Subhasis
    Nandi, Ganesh Chandra
    Singh, Pallavi
    Singh, M. S.
    TETRAHEDRON, 2009, 65 (49) : 10155 - 10161
  • [4] One-pot synthesis of 1,2,4,5-tetrasubstituted and 2,4,5-trisubstituted imidazoles by zinc oxide as efficient and reusable catalyst
    Kiumars Bahrami
    Mohammad M. Khodaei
    Akbar Nejati
    Monatshefte für Chemie - Chemical Monthly, 2011, 142 : 159 - 162
  • [5] One-pot synthesis of 1,2,4,5-tetrasubstituted and 2,4,5-trisubstituted imidazoles by zinc oxide as efficient and reusable catalyst
    Bahrami, Kiumars
    Khodaei, Mohammad M.
    Nejati, Akbar
    MONATSHEFTE FUR CHEMIE, 2011, 142 (02): : 159 - 162
  • [6] Catalyst-free one-pot synthesis of 2,4,5-tri- and 1,2,4,5-tetrasubstituted imidazoles
    Bandivadekar, Priyanka V.
    Chaturbhuj, Ganesh U.
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2024, 61 (03) : 430 - 438
  • [7] P2O5•SiO2: An efficient catalyst for the one-pot synthesis of 1,2,4,5-tetrasubstituted imidazoles
    Mirjalili, B. F.
    Bamoniri, A.
    Zarchi, M. A. Karimi
    Pouramini, F.
    OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2010, 4 (09): : 1384 - 1386
  • [8] L-Proline triflate as an efficient and reusable catalyst for the one-pot synthesis of 2,4,5-trisubstituted imidazoles and 1,2,4,5-tetrasubstituted imidazoles
    Li, Jianjun
    Lin, Shouwang
    Dai, Jiajia
    Su, Weike
    JOURNAL OF CHEMICAL RESEARCH, 2010, (04) : 196 - 199
  • [9] BF3•SiO2:: an efficient reagent system for the one-pot synthesis of 1,2,4,5-tetrasubstituted imidazoles
    Sadeghi, Bahareh
    Mirjalili, Bi Bi Fatemeh
    Hashemi, Mohammad M.
    TETRAHEDRON LETTERS, 2008, 49 (16) : 2575 - 2577
  • [10] ZSM-5-SO3H as an efficient catalyst for the one-pot synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles under solvent-free conditions
    Vosoughi, M.
    Mohebali, F.
    Bonakdar, A. Pesaran Seiied
    Lordegani, H. Ardeshiri
    Massah, A. R.
    BULGARIAN CHEMICAL COMMUNICATIONS, 2015, 47 (02): : 607 - 612