Kaolin-SO3H as an efficient catalyst for one- pot synthesis of 1,2,4,5-tetrasubstituted imidazoles

被引:0
|
作者
Mirjalili, Bibi Fatemeh [1 ]
Akrami, Hamidreza [1 ]
机构
[1] Yazd Univ, Dept Chem, Coll Sci, POB 89195-741, Yazd, Iran
来源
IRANIAN JOURNAL OF CATALYSIS | 2015年 / 5卷 / 02期
关键词
1,2,4,5-tetrasubstituted imidazoles; Kaolin-SO3H; Benzil; One-pot synthesis; Solvent-free conditions;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Kaolin-SO3H as a new solid acid is prepared via reaction of kaolin and chlorosulfonic acid. This natural based catalyst is very inexpensive and easy available. A simple, highly versatile and efficient synthesis of 1,2,4,5-tetrasubstituted imidazoles is achieved using Kaolin-SO3H as a catalyst at moderate temperature under solvent-free condition. The key advantages of this process are high yields with simple work-up using easy available inexpensive natural based catalyst.
引用
下载
收藏
页码:129 / 134
页数:6
相关论文
共 50 条
  • [41] Ag-TiO2 nanocomposite-catalyzed one-pot synthesis of 1,2,4,5-tetrasubstituted imidazoles: a green and benign approach
    Alipour, Soghra
    Vahdat, Seyed Mohammad
    Chekin, Fereshteh
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2021, 18 (09) : 2315 - 2321
  • [42] Wells-Dawson heteropolyacid supported on silica: a highly efficient catalyst for synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles
    Karimi, Ali Reza
    Alimohammadi, Zahra
    Amini, Mostafa M.
    MOLECULAR DIVERSITY, 2010, 14 (04) : 635 - 641
  • [43] One-pot synthesis of 1,2,4,5-tetrasubstituted imidazoles by a tandem three-component reaction of hydroxylamines, aldehydes and 2-azido acrylates
    Hu, Bao
    Ai, Ning
    Wang, Zhao
    Xu, Xiaoliang
    Li, Xiaonian
    ARKIVOC, 2012, : 222 - 228
  • [44] Catalyst-free synthesis of 1,2,4,5-tetrasubstituted imidazoles from arylamins, benzonitriles, arylglyoxals, and Meldrum's acid
    Mehrabi, Hossein
    Alizadeh-Bami, Farzaneh
    Ranjbar-Karimi, Reza
    TETRAHEDRON LETTERS, 2018, 59 (20) : 1924 - 1927
  • [45] Synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles in water using p-dodecylbenzenesulfonic acid as catalyst
    Das, Biswanath
    Kashanna, Jajula
    Kumar, Rathod Aravind
    Jangili, Paramesh
    MONATSHEFTE FUR CHEMIE, 2013, 144 (02): : 223 - 226
  • [46] One-pot synthesis of 1, 2, 4, 5-tetrasubstituted imidazoles promoted by nano-TiCl4.SiO2
    Mirjalili, B. F.
    Bamoniri, A. H.
    Zamani, L.
    SCIENTIA IRANICA, 2012, 19 (03) : 565 - 568
  • [47] An efficient synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted-1H-imidazoles
    Kidwai, M
    Saxena, S
    Ruby
    Rastogi, S
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (12) : 2051 - 2053
  • [48] Synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles in water using p-dodecylbenzenesulfonic acid as catalyst
    Biswanath Das
    Jajula Kashanna
    Rathod Aravind Kumar
    Paramesh Jangili
    Monatshefte für Chemie - Chemical Monthly, 2013, 144 : 223 - 226
  • [49] One pot synthesis of 1,2,4,5-tetrasubstituted-imidazoles catalyzed by trityl chloride in neutral media
    Moosavi-Zare, Ahmad Reza
    Asgari, Zhila
    Zare, Abdolkarim
    Zolfigol, Mohammad Ali
    Shekouhy, Mohsen
    RSC ADVANCES, 2014, 4 (105) : 60636 - 60639
  • [50] Magnetic nanoparticle-supported sulfonic acid as a green catalyst for the one-pot synthesis of 2,4,5-trisubstituted imidazoles and 1,2,4,5-tetrasubstituted imidazoles under solvent-free conditions
    Sakhdari, Mahnaz
    Amoozadeh, Ali
    Kolvari, Eskandar
    HETEROCYCLIC COMMUNICATIONS, 2021, 27 (01) : 71 - 78