HYDROGEN-BOND BASICITY OF NITROCOMPOUNDS

被引：44
|
作者：
LAURENCE, C [1 ]
BERTHELOT, M [1 ]
LUCON, M [1 ]
MORRIS, DG [1 ]
机构：
[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 03期
关键词：
D O I：
10.1039/p29940000491
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The hydrogen bond basicity scale pK(HB) (logarithm of the formation constant of 4-fluorophenol-base complexes in CCl4) has been measured for nitro-compounds. This thermodynamic basicity scale is correlated to a spectroscopic basicity scale. The Yukawa-Tsuno equation is obeyed in the nitroaromatics. We have shown that nitroenamines are the most basic nitro-compounds presently known and have hydrogen bond basicity comparable to tributylamine.
引用
收藏
页码：491 / 493
页数：3
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