HYDROGEN-BOND BASICITY OF NITROCOMPOUNDS

被引：44

作者：

LAURENCE, C ^{[1
]}

BERTHELOT, M ^{[1
]}

LUCON, M ^{[1
]}

MORRIS, DG ^{[1
]}

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 03期

关键词：

D O I：

10.1039/p29940000491

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The hydrogen bond basicity scale pK(HB) (logarithm of the formation constant of 4-fluorophenol-base complexes in CCl4) has been measured for nitro-compounds. This thermodynamic basicity scale is correlated to a spectroscopic basicity scale. The Yukawa-Tsuno equation is obeyed in the nitroaromatics. We have shown that nitroenamines are the most basic nitro-compounds presently known and have hydrogen bond basicity comparable to tributylamine.

引用

页码：491 / 493

页数：3

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