Dipolarity, hydrogen-bond basicity and hydrogen-bond acidity of aqueous poly(ethylene glycol) solutions

被引：53

作者：

Kim, IW

Jang, MD

Ryu, YK

Cho, EH

Lee, YK

Park, JH ^{[1
]}

机构：

[1] Yeungnam Univ, Dept Chem, Kyongsan 712749, South Korea

[2] Taegu Univ, Dept Chem Educ, Kyongsan 712714, South Korea

[3] Andong Info Tech, Dept Hlth & Hyg, Andong 762830, South Korea

来源：

ANALYTICAL SCIENCES | 2002年 / 18卷 / 12期

关键词：

D O I：

10.2116/analsci.18.1357

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Poly(ethylene glycol) (PEG) in water is known to alter the structure and/or state of water to give a different polarity from that of pure water. We determined using the solvatochromic comparison method the dipolarity/polarizability (pi*), hydrogen bond (HB) accepting basicity (beta) and HB donating acidity (alpha) of aqueous solutions of PEGs of variegated molecular weights at different concentrations in order to understand the influence of the polymer on these properties of water. It was observed that PEG decreases alpha for water while it does not change pi* and beta appreciably in the range of the molecular weight and compositions studied.

引用

页码：1357 / 1360

页数：4

共 50 条

[1] Dipolarity, Hydrogen-Bond Basicity and Hydrogen-Bond Acidity of Aqueous Poly(ethylene glycol) Solutions
In-Whan Kim
Myung Duk Jang
Young Kyun Ryu
Eun Hee Cho
Young Kyu Lee
Jung Hag Park
[J]. Analytical Sciences, 2002, 18 : 1357 - 1360
[2] The Hydrogen-bond Basicity of Carbenes
Abraham, Michael H.
Elguero, Jose
Alkorta, Ibon
[J]. CROATICA CHEMICA ACTA, 2018, 91 (01) : 121 - 124
[3] HYDROGEN-BOND BASICITY OF NITROCOMPOUNDS
LAURENCE, C
BERTHELOT, M
LUCON, M
MORRIS, DG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (03): : 491 - 493
[4] HYDROGEN-BOND BASICITY OF NITRILES
BERTHELOT, M
HELBERT, M
LAURENCE, C
LEQUESTEL, JY
[J]. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1993, 6 (05) : 302 - 306
[5] HYDROGEN-BOND BASICITY OF THIOAMIDES AND THIOUREAS
LAURENCE, C
BERTHELOT, M
LEQUESTEL, JY
ELGHOMARI, MJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (11): : 2075 - 2079
[6] Solvation Descriptors for Zwitterionic α-Aminoacids; Estimation of Water-Solvent Partition Coefficients, Solubilities, and Hydrogen-Bond Acidity and Hydrogen-Bond Basicity
Abraham, Michael H.
Acree, William E., Jr.
[J]. ACS OMEGA, 2019, 4 (02): : 2883 - 2892
[7] "Hydridic Hydrogen-Bond Donors" Are Not Hydrogen-Bond Donors
Santos, Lucas de Azevedo
Vermeeren, Pascal
Bickelhaupt, F. Matthias
Guerra, Celia Fonseca
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (37) : 25701 - 25709
[8] Alternative probe for the determination of the hydrogen-bond acidity of ionic liquids and their aqueous solutions
Madeira, Pedro P.
Passos, Helena
Gomes, Joana
Coutinho, Joao A. P.
Freire, Mara G.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (18) : 11011 - 11016
[9] MEASUREMENT OF SOLUTE DIPOLARITY POLARIZABILITY AND HYDROGEN-BOND ACIDITY BY INVERSE GAS-CHROMATOGRAPHY
LI, JJ
ZHANG, YK
DALLAS, AJ
CARR, PW
[J]. JOURNAL OF CHROMATOGRAPHY, 1991, 550 (1-2): : 101 - 134
[10] Theoretical prediction of the hydrogen-bond basicity pKHB
Lamarche, O
Platts, JA
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (02) : 457 - 466

← 1 2 3 4 5 →