A CONVENIENT SYNTHESIS OF VINYL SULFIDES

被引：21
|
作者：
KATRITZKY, AR [1 ]
AFRIDI, AS [1 ]
KUZMIERKIEWICZ, W [1 ]
机构：
[1] UNIV FLORIDA,CTR HETEROCYCL CPDS,GAINESVILLE,FL 32611
来源：
HELVETICA CHIMICA ACTA | 1991年 / 74卷 / 08期
基金：
俄罗斯科学基金会; 美国国家科学基金会; 美国国家卫生研究院;
关键词：
D O I：
10.1002/hlca.19910740830
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
tert-Alkyl sulfides, with an alpha-(1H-benzotriazol-1-yl) group 6 and 13, are readily prepared from N-[(arylthio)methyl]-1H-benzotriazoles 3 and N-(11), respectively, by reaction with BuLi and then with the appropriate electrophile. The tert-alkyl sulfides 6 and 13 are smoothly converted by BF3.OEt2 into vinyl sulfides 5, 7 or 12, respectively, in satisfactory yields.
引用
收藏
页码：1931 / 1935
页数：5
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