COPPER(II) NITRATE COMPOUNDS WITH HETEROCYCLIC LIGANDS - STRUCTURES OF [CU(NO3)(2,2'-DIPYRIDYL)(2)][NO3]CENTER-DOT-H2O AND [CU(H2O)(1,10-PHENANTHROLINE)(2)][NO3](2)

被引：54
|
作者：
CATALAN, KJ
JACKSON, S
ZUBKOWSKI, JD
PERRY, DL
VALENTE, EJ
FELIU, LA
POLANCO, A
机构：
[1] JACKSON STATE UNIV,DEPT CHEM,JACKSON,MS 39217
[2] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,BERKELEY,CA 94720
[3] MISSISSIPPI COLL,DEPT CHEM,CLINTON,MS 39056
[4] UNIV METROPOLITANA,DEPT NAT SCI,RIO PIEDRAS,PR 00928
来源：
POLYHEDRON | 1995年 / 14卷 / 15-16期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/0277-5387(95)00011-G
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal and molecular structures of [Cu(NO3)(2,2'-dipyridyl)(2)](NO3). H2O (1) and [Cu(H2O)(1,10-phenanthroline)(2)](NO3)(2) (2) have been determined by single crystal X-ray diffraction. The copper cation in 1 displays pseudo-octahedral geometry with ligand nitrogen donors occupying four positions, a coordinated nitrate oxygen a fifth and a nonbonded oxygen a sixth. The copper cation in 2 shows a trigonal bipyramidal geometry with ligand nitrogen donors occupying the axial and two of the equatorial positions, and a coordinated aqua oxygen the other.
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收藏
页码：2165 / 2171
页数：7
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