COPPER(II) NITRATE COMPOUNDS WITH HETEROCYCLIC LIGANDS - STRUCTURES OF [CU(NO3)(2,2'-DIPYRIDYL)(2)][NO3]CENTER-DOT-H2O AND [CU(H2O)(1,10-PHENANTHROLINE)(2)][NO3](2)

被引：54

作者：

CATALAN, KJ

JACKSON, S

ZUBKOWSKI, JD

PERRY, DL

VALENTE, EJ

FELIU, LA

POLANCO, A

机构：

[1] JACKSON STATE UNIV,DEPT CHEM,JACKSON,MS 39217

[2] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,BERKELEY,CA 94720

[3] MISSISSIPPI COLL,DEPT CHEM,CLINTON,MS 39056

[4] UNIV METROPOLITANA,DEPT NAT SCI,RIO PIEDRAS,PR 00928

来源：

POLYHEDRON | 1995年 / 14卷 / 15-16期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0277-5387(95)00011-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structures of [Cu(NO3)(2,2'-dipyridyl)(2)](NO3). H2O (1) and [Cu(H2O)(1,10-phenanthroline)(2)](NO3)(2) (2) have been determined by single crystal X-ray diffraction. The copper cation in 1 displays pseudo-octahedral geometry with ligand nitrogen donors occupying four positions, a coordinated nitrate oxygen a fifth and a nonbonded oxygen a sixth. The copper cation in 2 shows a trigonal bipyramidal geometry with ligand nitrogen donors occupying the axial and two of the equatorial positions, and a coordinated aqua oxygen the other.

引用

页码：2165 / 2171

页数：7

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