RHODIUM-CATALYZED SYNTHESIS OF 3-METHYL-9,9A-DIHYDRO-1H-CYCLOPENTA[B]QUINOLIN-2(4H)-ONE

被引：0
|
作者：
Zaware, Nilesh [1 ]
Ohlmeyer, Michael [1 ]
机构：
[1] Mt Sinai Sch Med, Dept Struct & Chem Biol, New York, NY 10029 USA
来源：
HETEROCYCLIC LETTERS | 2015年 / 5卷 / 04期
基金：
美国国家卫生研究院;
关键词：
Pauson Khand type reaction; Rhodium catalysis; Vinylogous amide;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
3-Methyl-9,9a-dihydro-1H-cyclopenta[b]quinolin-2(4H)-one 1 was synthesized from squaric acid diisopropoxy ester. Key reactions involved the Pauson Khand-type rhodium-catalyzed decarbonylative cycloaddition of cyclobutenediones with a pendant alkene, and the Mitsunobu reaction.
引用
收藏
页码：525 / 527
页数：3
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