RHODIUM-CATALYZED SYNTHESIS OF 3-METHYL-9,9A-DIHYDRO-1H-CYCLOPENTA[B]QUINOLIN-2(4H)-ONE

被引：0

作者：

Zaware, Nilesh ^{[1
]}

Ohlmeyer, Michael ^{[1
]}

机构：

[1] Mt Sinai Sch Med, Dept Struct & Chem Biol, New York, NY 10029 USA

来源：

HETEROCYCLIC LETTERS | 2015年 / 5卷 / 04期

基金：

美国国家卫生研究院;

关键词：

Pauson Khand type reaction; Rhodium catalysis; Vinylogous amide;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-Methyl-9,9a-dihydro-1H-cyclopenta[b]quinolin-2(4H)-one 1 was synthesized from squaric acid diisopropoxy ester. Key reactions involved the Pauson Khand-type rhodium-catalyzed decarbonylative cycloaddition of cyclobutenediones with a pendant alkene, and the Mitsunobu reaction.

引用

页码：525 / 527

页数：3

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