Synthesis and crystal structure of 4-(4-bromophenyl)-3,4-dihydro-6-methyl quinolin-2(1H)-one

被引：0
|
作者：
Yu Chen-Xia
Zhu Xiao-Tong
Yao Chang-Sheng
Tu Shu-Jiang [1 ]
机构：
[1] Xuzhou Normal Univ, Dept Chem, Xuzhou 221116, Peoples R China
[2] Key Lab Biotechnol Med Plants Jaingsu Province, Xuzhou 221116, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 26卷 / 05期
关键词：
quinoline; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound (C16H14BrNO) has been synthesized by the reaction of p-tolylamine, Meldrum's acid and 4-bromo-benzaldehyde, and its structure was characterized by IR, H-1 NMR and X-ray single-crystal diffraction. The crystal belongs to monoclinic, space group P2(1)/n with a = 7.6850(11), b = 8.3004(11), c = 21.301(3) angstrom,beta = 95.110(3)degrees, V = 1353.4(3) angstrom(3), M-r,= 316.19, Z = 4, D-c, = 1.552 g/cm(3), mu(MoK alpha) = 3.028 mm(-1), F(000) = 640, the final R = 0.0345 and wR = 0.0768. X-ray analysis reveals that the atoms of C(1), C(2), C(3), C(4), C(5) and N(1) form a six-membered ring of boat conformation.
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收藏
页码：533 / 536
页数：4
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