C-(N,N-DIALKYLAMINO)-SUBSTITUTED ARSAALKENES - A SIMPLE METHOD FOR THE PREPARATION AND EXAMPLES OF THEIR REACTIVITY

被引：2
|
作者：
IONKIN, AS
NIKOLAEVA, NV
MUSIN, RZ
EFREMOV, YY
ARBUZOV, BA
机构：
[1] A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the USSR Academy of Sciences, Kazan 420083, USSR, A. E. Arbuzov Street
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1992年 / 66卷 / 1-4期
关键词：
ARSINE; AMIDACETALS; ARSAALKENES; DITHIOARSARANES;
D O I：
10.1080/10426509208038354
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple method for the preparation of C-(N, N-dialkylamino)-substituted arsaalkenes 4a, b is suggested. The -As=C< bond in this kind of compounds is shown to react with sulfur to yield dithioarsaranes, which are dimeric in the solid phase and monomeric in the gas phase. © 1992, Taylor & Francis Group, LLC. All rights reserved.
引用
收藏
页码：257 / 260
页数：4
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