Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations

被引：1
|
作者：
Munin-Cruz, Paula [1 ]
Reigosa, Francisco [1 ]
Rua-Sueiro, Marcos [1 ]
Ortigueira, Juan M. [1 ]
Pereira, M. Teresa [1 ]
Vila, Jose M. [1 ]
机构：
[1] Univ Santiago de Compostela, Dept Quim Inorgan, Santiago De Compostela 15782, Spain
来源：
CHEMISTRYOPEN | 2020年 / 9卷 / 11期
关键词：
palladium; diphosphine; azides; iminophosphorane; density functional theory; CYCLOMETALATED COMPLEXES; PHOSPHORESCENT; CAGE;
D O I：
10.1002/open.202000253
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A theoretical and experimental study of tetradentate [C,N : C,N] iminophosphorane palladacycles was carried out for the purpose of elucidating their behavior as compared to the parent Schiff base analogues to determine the prospect of encountering new A-frame structures for the iminophosphorane derivatives. The DFT calculations were in agreement with the experimental results regarding the performance of these ligands. New insights into the chemistry of the related dinuclear species have been obtained.
引用
收藏
页码：1190 / 1194
页数：5
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