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CHEMICAL-PROPERTIES OF LIGNIN FROM ARALIA-CORDATA

被引：21
|
作者：
HIBINO, T
SHIBATA, D
ITO, T
TSUCHIYA, D
HIGUCHI, T
POLLET, B
LAPIERRE, C
机构：
[1] COLL AGR & VET MED,DEPT FORESTRY,SETAGAYA KU,TOKYO 154,JAPAN
[2] MITSUI PLANT BIOTECHNOL RES INST,TSUKUBA,IBARAKI 305,JAPAN
[3] INRA,CHIM BIOL LAB,PARIS,FRANCE
来源：
PHYTOCHEMISTRY | 1994年 / 37卷 / 02期
关键词：
ARALIA CORDATA; ARALIACEAE; GUAIACYL-SYRINGYL LIGNIN; NITROBENZENE OXIDATION; THIOACIDOLYSIS;
D O I：
10.1016/0031-9422(94)85076-3
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Lignin from Aralia cordata, was isolated and characterized spectrometrically and by chemical degradations. IR and C-13 NMR spectra of the dioxan lignin showed a pattern of guaiacyl (G)-syringyl (Sf lignin esterified with p-hydroxybenzoate. Alkaline hydrolysis of the lignin gave p-hydroxybenzoic acid. Molar ratios of the main syringyl to guaiacyl monomers recovered from alkaline nitrobenzene oxidation and from thioacidolysis are 1.3 and 1.2, respectively, indicating that A. cordata contains a guaiacyl-syringyl lignin, although the amount of syringyl lignin is a little lower than that in normal angiosperm wood.
引用
收藏
页码：445 / 448
页数：4
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