FREE RADICAL-BASED ANNULATION OF ALKENES YIELDING FUSED CYCLOHEPTANONES

被引：12
|
作者：
ZHANG, W [1 ]
HUA, Y [1 ]
HOGE, G [1 ]
DOWD, P [1 ]
机构：
[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 23期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/S0040-4039(00)76687-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Stereospecific annulation of cyclic alkenes for the preparation of cis-fused seven-membered ring systems was accomplished by sequential [2 + 2] cycloaddition, exo-allylation, hydrohalogenation, and free radical ring expansion. The new strategy extends our recently developed cyclobutanone-based ring expansion reactions.
引用
收藏
页码：3865 / 3868
页数：4
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