FREE RADICAL-BASED ANNULATION OF ALKENES YIELDING FUSED CYCLOHEPTANONES

被引：12

作者：

ZHANG, W ^{[1
]}

HUA, Y ^{[1
]}

HOGE, G ^{[1
]}

DOWD, P ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 23期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)76687-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereospecific annulation of cyclic alkenes for the preparation of cis-fused seven-membered ring systems was accomplished by sequential [2 + 2] cycloaddition, exo-allylation, hydrohalogenation, and free radical ring expansion. The new strategy extends our recently developed cyclobutanone-based ring expansion reactions.

引用

页码：3865 / 3868

页数：4

共 50 条

[21] A new radical-based route to calothrixin B
Bennasar, ML
Roca, T
Ferrando, F
ORGANIC LETTERS, 2006, 8 (04) : 561 - 564
[22] A RADICAL-BASED SYNTHESIS OF (Z,Z)-TRICYCLOHEXAPRENOL
HEISSLER, D
JENN, T
NAGANO, H
TETRAHEDRON LETTERS, 1991, 32 (51) : 7587 - 7590
[23] S-adenosylmethionine and radical-based catalysis
Grillo, M. A.
Colombatto, S.
AMINO ACIDS, 2007, 32 (02) : 197 - 202
[24] FREE-RADICAL ANNULATION OF CYCLOPENTANE RING
CEKOVIC, Z
SAICIC, R
TETRAHEDRON LETTERS, 1986, 27 (48) : 5893 - 5896
[25] S-adenosylmethionine and radical-based catalysis
M. A. Grillo
S. Colombatto
Amino Acids, 2007, 32 : 197 - 202
[26] Radical-Based Coordination Polymers as a Platform for Magnetoluminescence
Kimura, Shun
Matsuoka, Ryota
Kimura, Shojiro
Nishihara, Hiroshi
Kusamoto, Tetsuro
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (15) : 5610 - 5615
[27] Radical-Based Synthesis and Modification of Amino Acids
Troyano, Francisco Jose Aguilar
Merkens, Kay
Anwar, Khadijah
Gomez-Suarez, Dr Adrian
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (03) : 1098 - 1115
[28] ORGANOSILANES AS RADICAL-BASED REDUCING AGENTS IN SYNTHESIS
CHATGILIALOGLU, C
ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (04) : 188 - 194
[29] Novel phosphorus radical-based routes to horsfiline
Murphy, JA
Tripoli, R
Khan, TA
Mail, UW
ORGANIC LETTERS, 2005, 7 (15) : 3287 - 3289
[30] Unified, radical-based approach for the synthesis of spiroketals
de Greef, Michiel
Zard, Samir Z.
ORGANIC LETTERS, 2007, 9 (09) : 1773 - 1776

← 1 2 3 4 5 →