MATRIX-ASSISTED LASER DESORPTION MASS-SPECTROMETRY OF LIGNINS

被引:48
|
作者
METZGER, JO
BICKE, C
FAIX, O
TUSZYNSKI, W
ANGERMANN, R
KARAS, M
STRUPAT, K
机构
[1] BUNDESFORSCH ANSTALT FORST & HOLZWIRTSCHAFT,HAMBURG,GERMANY
[2] UNIV OLDENBURG,FACHBEREICH PHYS,W-2900 OLDENBURG,GERMANY
[3] UNIV MUNSTER,INST MED PHYS,W-4400 MUNSTER,GERMANY
来源
关键词
D O I
10.1002/anie.199207621
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The matrix-supported laser desorption technique proved to be quick, sensitive, and informative in the characterization of lignins. The technique yields the molecular weight distribution directly (for birch lignin up to about 16 000 Da), while the well-resolved fine structure of the spectrum confirms the existence of oligomers from trimers through to nonamers. The hyperfine structure reflects the complicated structure of lignin, constructed of monomeric units that are linked to one another through various types of bonds.
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页码:762 / 764
页数:3
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