SYNTHESIS AND CRYSTAL-STRUCTURE OF THE NOVEL CYCLOPALLADATED COMPLEX DI(MU,N-S-ETA(2)-QUINOLINE-2-THIOLATE)-BIS[(N,N-DIMETHYLBENZYLAMINE-C(2),N) PALLADIUM(II)]

被引：0
|
作者：
CAIRES, ACF [1 ]
MAURO, AE [1 ]
SANTOS, RHD [1 ]
GAMBARDELLA, MTP [1 ]
LECHAT, JR [1 ]
机构：
[1] USP,INST QUIM & FIS SAO CARLOS,BR-13560 SAO CARLOS,SP,BRAZIL
来源：
GAZZETTA CHIMICA ITALIANA | 1993年 / 123卷 / 09期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The compound di(mu,N-Seta2-2-quinoline-2-thiolate)-bis[(N,N-dimethylbenzylamine-C2,N)palladium(II)] was synthesized and studied by IR, NMR and X-ray diffraction: monoclinic, a = 20.138(3), b = 10.831(1), c = 14.973(2) angstrom, beta = 98.04(1)-degrees, Z = 4, space group P2(1)/c, R = 0.032. The compound is dimeric with the two [Pd(N,N-dimethylbenzylamine)]moieties being connected by the two vicinal bridging eta2-N,S-quinoline-2-thiolate anions in a square-planar coordination geometry for the palladium atoms.
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页码：495 / 497
页数：3
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