SYNTHESIS AND CRYSTAL-STRUCTURE OF THE NOVEL CYCLOPALLADATED COMPLEX DI(MU,N-S-ETA(2)-QUINOLINE-2-THIOLATE)-BIS[(N,N-DIMETHYLBENZYLAMINE-C(2),N) PALLADIUM(II)]

被引：0

作者：

CAIRES, ACF ^{[1
]}

MAURO, AE ^{[1
]}

SANTOS, RHD ^{[1
]}

GAMBARDELLA, MTP ^{[1
]}

LECHAT, JR ^{[1
]}

机构：

[1] USP,INST QUIM & FIS SAO CARLOS,BR-13560 SAO CARLOS,SP,BRAZIL

来源：

GAZZETTA CHIMICA ITALIANA | 1993年 / 123卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound di(mu,N-Seta2-2-quinoline-2-thiolate)-bis[(N,N-dimethylbenzylamine-C2,N)palladium(II)] was synthesized and studied by IR, NMR and X-ray diffraction: monoclinic, a = 20.138(3), b = 10.831(1), c = 14.973(2) angstrom, beta = 98.04(1)-degrees, Z = 4, space group P2(1)/c, R = 0.032. The compound is dimeric with the two [Pd(N,N-dimethylbenzylamine)]moieties being connected by the two vicinal bridging eta2-N,S-quinoline-2-thiolate anions in a square-planar coordination geometry for the palladium atoms.

引用

页码：495 / 497

页数：3

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