THE ELECTRONIC-STRUCTURE OF ACTINYL IONS - THE EXCITED-STATE ABSORPTION-SPECTRUM OF CS2UO2CL4 .8.

被引：18

作者：

DENNING, RG

MORRISON, ID

机构：

[1] Inorganic Chemistry Laboratory, Oxford, OX1 3QR, South Parks Road

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(91)87123-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The polarised excited-state optical absorption spectrum of a single crystal of Cs2UO2Cl4 at 77 K is reported. The intense absorption band near 580 nm is polarised parallel to the U-O axis. This observation is used to locate the highest-filled gerade orbital and to establish the role of the 6d orbitals in the formation of the uranyl ion.

引用

页码：101 / 104

页数：4

共 50 条

[21] ELECTRONIC-STRUCTURE AND X-RAY ABSORPTION-SPECTRUM OF RUTILE TIO2
POUMELLEC, B
DURHAM, PJ
GUO, GY
JOURNAL OF PHYSICS-CONDENSED MATTER, 1991, 3 (42) : 8195 - 8204
[22] ELECTRONIC-STRUCTURE AND ABSORPTION-SPECTRUM OF COPPER(II)-BIS(2-IMINE-4-AMINE METHYLPENTANE) NITRATE
OBERT, T
CHEMICKE ZVESTI, 1972, 26 (02): : 97 - &
[23] ELECTRONIC-ENERGY TRANSFER IN ACTINYL CRYSTALS .3. MIGRATION AND TRAPPING IN CS2UO2CL4-XBRX
DENNING, RG
IRONSIDE, CN
SNELLGROVE, TR
THORNE, JRG
MOLECULAR PHYSICS, 1982, 47 (02) : 443 - 456
[24] AN EVALUATION OF THE EXCITED-STATE ABSORPTION-SPECTRUM OF RU(BPY)3(2+) IN AQUEOUS AND ACETONITRILE SOLUTIONS
YOSHIMURA, A
HOFFMAN, MZ
SUN, H
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1993, 70 (01) : 29 - 33
[25] EXCITED-STATE ABSORPTION-SPECTRUM OF F2+ CENTERS AND THE H2+ MOLECULAR-ION MODEL
MOLLENAUER, LF
PHYSICAL REVIEW LETTERS, 1979, 43 (20) : 1524 - 1528
[26] Electronic structure and spectrum of UO2+2 and UO2Cl2-4 -: art. no. 204309
Pierloot, K
van Besien, E
JOURNAL OF CHEMICAL PHYSICS, 2005, 123 (20):
[27] ANALYSIS OF ELECTRONIC-STRUCTURE OF COMPLEXES UCL6 AND [UO2CL4]2-
VOLODKO, LV
TITKOV, EF
DOKLADY AKADEMII NAUK SSSR, 1977, 237 (04): : 844 - 847
[28] THE ELECTRONIC-STRUCTURE OF ACTINYL IONS .5. F-F TRANSITIONS IN [NPO2CL4]= AND [NPO2(NO3)3]-
DENNING, RG
NORRIS, JOW
BROWN, D
MOLECULAR PHYSICS, 1982, 46 (02) : 287 - 323
[29] ABSORPTION-SPECTRUM AND QUANTUM YIELD OF FORMATION OF THE LOWEST TRIPLET EXCITED-STATE OF RU(BPY)-3(2-) IN WATER
BENSASSON, RV
SALET, C
BALZANI, V
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE B, 1979, 289 (02): : 41 - 43
[30] LASER FLASH-PHOTOLYSIS OF 3-PHENYLCYCLOPENT-2-ENONE - ABSORPTION-SPECTRUM AND REACTIVITY OF ITS TRIPLET EXCITED-STATE
KELLY, JM
MCMURRY, TBH
WORK, DN
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) : 280 - 281

← 1 2 3 4 5 →