THE ELECTRONIC-STRUCTURE OF ACTINYL IONS - THE EXCITED-STATE ABSORPTION-SPECTRUM OF CS2UO2CL4 .8.

被引：18
|
作者：
DENNING, RG
MORRISON, ID
机构：
[1] Inorganic Chemistry Laboratory, Oxford, OX1 3QR, South Parks Road
来源：
CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(91)87123-S
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The polarised excited-state optical absorption spectrum of a single crystal of Cs2UO2Cl4 at 77 K is reported. The intense absorption band near 580 nm is polarised parallel to the U-O axis. This observation is used to locate the highest-filled gerade orbital and to establish the role of the 6d orbitals in the formation of the uranyl ion.
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页码：101 / 104
页数：4
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