DELIVERY-CONTROL IN ORGANIC-REACTIVITY

被引：23
|
作者：
SHERROD, MJ [1 ]
MENGER, FM [1 ]
机构：
[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期
关键词：
D O I：
10.1016/0040-4039(90)87007-M
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A large portion of the energy requirements of an intramolecular hydride transfer was shown to entail a carbon skeleton distortion that delivers the hydrogen to the recipient carbon. Only after a critical distance is reached does actual chemical reaction begin. © 1990.
引用
收藏
页码：459 / 462
页数：4
相关论文
共 50 条
  • [31] Reactivity of organic σ,σ,σ,σ,σ-pentaradicals
    Max, Joann P.
    Ma, Xin
    Kotha, Raghavendhar R.
    Ding, Duanchen
    Milton, Jacob
    Nash, John J.
    Kenttama, Hilkka, I
    [J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2019, 435 : 280 - 290
  • [32] Organic Ring-Opening Polymerization Catalysts: Reactivity Control by Balancing Acidity
    Lin, Binhong
    Waymouth, Robert M.
    [J]. MACROMOLECULES, 2018, 51 (08) : 2932 - 2938
  • [33] IMPACT OF REACTIVITY CRITERIA ON ORGANIC EMISSION CONTROL STRATEGIES FOR LOS-ANGELES
    TRIJONIS, JC
    DIMITRIADES, B
    ARLEDGE, K
    [J]. JOURNAL OF THE AIR POLLUTION CONTROL ASSOCIATION, 1978, 28 (10): : 1021 - 1029
  • [34] IMPACT OF REACTIVITY CRITERIA ON ORGANIC EMISSION CONTROL STRATEGIES FOR LOS ANGELES.
    Trijonis, John C.
    Dimitriades, Basil
    Arledge, Kenneth
    [J]. 1977, 2 (24):
  • [35] Local biomass control on the composition and reactivity of particulate organic matter in aquatic environments
    Florida International University
    [J].
  • [36] Design of silver(I)-heteropolyacids: toward the molecular control of reactivity in organic chemistry
    Borghese, Sophie
    Louis, Benoit
    Blanc, Aurelien
    Pale, Patrick
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (06) : 981 - 986
  • [37] INOR 95-Control of reactivity and fluorescence within metal-organic solids
    Georgiev, Ivan G.
    MacGillivray, Leonard R.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 232
  • [38] Organic reactivity in liquid ammonia
    Ji, Pengju
    Atherton, John
    Page, Michael I.
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (30) : 5732 - 5739
  • [39] Reactivity of indolizines in organic synthesis
    Elattar, Khaled M.
    Youssef, Ibrahim
    Fadda, Ahmed A.
    [J]. SYNTHETIC COMMUNICATIONS, 2016, 46 (09) : 719 - 744
  • [40] Organic reactivity special issue
    Fastrez, J
    Ruasse, MF
    [J]. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1998, 11 (8-9) : 505 - 507
12345