Design of silver(I)-heteropolyacids: toward the molecular control of reactivity in organic chemistry

被引：32

作者：

Borghese, Sophie ^{[1
]}

Louis, Benoit ^{[1
]}

Blanc, Aurelien ^{[1
]}

Pale, Patrick ^{[1
]}

机构：

[1] Univ Strasbourg, Lab Synth & Reactivite Organ, Associe CNRS, Inst Chim, F-67081 Strasbourg, France

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 06期

关键词：

AXIALLY DISSYMMETRIC MOLECULES; ALUMINUM-HYDRIDE REAGENTS; C-H INSERTION; SUPRAMOLECULAR CHEMISTRY; TUNGSTOPHOSPHORIC ACID; HETEROPOLY COMPOUNDS; ENANTIOSELECTIVE REDUCTION; 12-TUNGSTOPHOSPHORIC ACID; HETEROGENEOUS CATALYST; ASYMMETRIC-SYNTHESIS;

D O I：

10.1039/c1cy00154j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of silver polyoxometalates (POMs) have been prepared, characterized and studied as catalysts. By tuning the amount of silver and POM acidity, a very effective and reusable catalyst was obtained, allowing the synthesis of various furans and pyrroles in high yields under mild conditions.

引用

页码：981 / 986

页数：6

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