INFRARED STUDIES OF THE PHASE-TRANSITION IN THE ORGANIC CHARGE-TRANSFER SALT (ET)(2)C(CN)(3)

被引：3
|
作者：
SWIETLIK, R [1 ]
KUSHCH, LA [1 ]
机构：
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
来源：
SYNTHETIC METALS | 1995年 / 70卷 / 1-3期
关键词：
D O I：
10.1016/0379-6779(94)02725-E
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Polarized reflectance spectra from single crystals and powder absorption spectra of (ET)(2)C(CN)(3) salt are measured in the middle IR region. The metal-insulator phase transition influences the IR spectra especially within the range of C=C vibrations. The strong coupling of electrons with v27(b(1u)) mode (antisymmetric stretching of C=C ring bonds) is observed.
引用
收藏
页码：975 / 976
页数：2
相关论文
共 50 条
  • [41] PHASE-TRANSITION OF THE MIXED-STACK CHARGE-TRANSFER TTF-P-CHLORANIL SINGLE-CRYSTALS
    MITANI, T
    TOKURA, Y
    KANEKO, Y
    TAKAOKA, K
    KODA, T
    SAITO, G
    SYNTHETIC METALS, 1987, 19 (1-3) : 515 - 520
  • [42] SPECTRAL PROPERTIES OF TRAP STATES AND THE ORIENTATIONAL PHASE-TRANSITION IN NAPHTHALENE TETRACYANOBENZENE CHARGE-TRANSFER CRYSTAL DOPED WITH PYRENE
    KOZANKIEWICZ, B
    PROCHOROW, J
    CORVAJA, C
    MANIERO, AL
    JOURNAL OF LUMINESCENCE, 1994, 62 (3-4) : 179 - 186
  • [43] Coordination bond formation at charge-transfer phase transition in (BDTA)2[Co(mnt)2]
    Umezono, Yoshikatsu
    Fujita, Wataru
    Awaga, Kunio
    Journal of the American Chemical Society, 2006, 128 (04): : 1084 - 1085
  • [44] Coordination bond formation at charge-transfer phase transition in (BDTA)2[Co(mnt)2]
    Umezono, Y
    Fujita, W
    Awaga, K
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (04) : 1084 - 1085
  • [45] First-order phase transition in the organic metal κ-(BETS)2C(CN)3
    Narymbetov, BZ
    Canadell, E
    Togonidze, T
    Khasanov, SS
    Zorina, LV
    Shibaeva, RP
    Kobayashi, H
    JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (02) : 332 - 336
  • [46] Infrared and Raman studies of the charge ordering in the organic semiconductor K-[Et4N][Co(CN)6(ET)4]•3H2O
    Swietlik, R
    Ouahab, L
    Guillevic, J
    Yakushi, K
    MACROMOLECULAR SYMPOSIA, 2004, 212 : 219 - 224
  • [47] Model of photo-induced neutral-ionic phase transition in organic charge-transfer salts
    Yartsev, VM
    OPTICAL MATERIALS, 1998, 9 (1-4) : 507 - 510
  • [48] HIGH-PRESSURE STUDIES OF THE NEUTRAL-TO-IONIC TRANSITION IN SOME ORGANIC CHARGE-TRANSFER SOLIDS
    JURGENSEN, CW
    DRICKAMER, HG
    CHEMICAL PHYSICS LETTERS, 1986, 125 (5-6) : 554 - 556
  • [49] THE PHASE-DIAGRAM OF 2-1 CATIONIC ORGANIC CHARGE-TRANSFER SALTS
    MAZUMDAR, S
    LIN, HQ
    CAMPBELL, DK
    SYNTHETIC METALS, 1991, 43 (03) : 4047 - 4050
  • [50] Multiferroicity in the Mott Insulating Charge-Transfer Salt κ-(BEDT-TTF)2Cu[N(CN)2]Cl
    Lang, Michael
    Lunkenheimer, Peter
    Mueller, Jens
    Loidl, Alois
    Hartmann, Benedikt
    Hoang, Nguyen H.
    Gati, Elena
    Schubert, Harald
    Schlueter, John A.
    IEEE TRANSACTIONS ON MAGNETICS, 2014, 50 (06)
12345