INFRARED STUDIES OF THE PHASE-TRANSITION IN THE ORGANIC CHARGE-TRANSFER SALT (ET)(2)C(CN)(3)

被引:3
|
作者
SWIETLIK, R [1 ]
KUSHCH, LA [1 ]
机构
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
关键词
D O I
10.1016/0379-6779(94)02725-E
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polarized reflectance spectra from single crystals and powder absorption spectra of (ET)(2)C(CN)(3) salt are measured in the middle IR region. The metal-insulator phase transition influences the IR spectra especially within the range of C=C vibrations. The strong coupling of electrons with v27(b(1u)) mode (antisymmetric stretching of C=C ring bonds) is observed.
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页码:975 / 976
页数:2
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