INVESTIGATION OF AN ELECTRONIC ELECTRODE IN HEXAMETHYLPHOSPHORIC TRIAMIDE BY IMPEDANCE MEASUREMENTS

被引：0

作者：

OVSYANNIKOVA, EV ^{[1
]}

KRISHTALIK, LI ^{[1
]}

NOVITSKII, SP ^{[1
]}

BURENKOV, II ^{[1
]}

ALPATOVA, NM ^{[1
]}

机构：

[1] ACAD SCI USSR,INST RAW MINERAL PROC,NOVOSIBIRSK,USSR

来源：

SOVIET ELECTROCHEMISTRY | 1982年 / 18卷 / 07期

关键词：

ELECTRONIC ELECTRODE - LITHIUM CHLORIDE;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The behavior of an equilibrium electronic electrode in a solution of lithium chloride in hexamethylphosphoric triamide containing solvated electrons has been investigated by impedance methods. It is shown that in the system investigated, in which the concentration of the potential-determining particles, i. e. , the solvated electrons, and the state of the surface of the metallic electrode can vary with time, reliable information on the components of the impedance can be obtained only with the aid of a high-speed device for measuring the impedance. The decisive influence of the state of the electrode surface, assigned by preliminary polarization of the electrode, has been established.

引用

页码：769 / 775

页数：7

共 50 条

[41] NEW TYPE OF PHOSPHORUS COMPOUND BY AUTOCONDENSATION OF HEXAMETHYLPHOSPHORIC TRIAMIDE
ANSELMI, C
MACCHIA, B
MACCHIA, F
MONTI, L
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (19): : 1152 - &
[42] LASER PHOTOLYSIS OF SOLUTIONS OF SOLVATED ELECTRONS IN HEXAMETHYLPHOSPHORIC TRIAMIDE
MALTSEV, EI
GOLOVANOV, VV
ZOLOTAREVSKII, VI
VANNIKOV, AV
HIGH ENERGY CHEMISTRY, 1977, 11 (01) : 79 - 81
[43] ESTIMATION OF THE RELAXATION ENERGY OF SOLVATED ELECTRONS IN HEXAMETHYLPHOSPHORIC TRIAMIDE SOLUTION FROM PHOTON-EMISSION MEASUREMENTS
MURAKOSHI, K
UOSAKI, K
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 308 (1-2) : 351 - 356
[44] FACILE PREPARATION OF OXODIPEROXYMOLYBDENUM(PYRIDINE) (HEXAMETHYLPHOSPHORIC TRIAMIDE) (MOOPH)
DANIEWSKI, AR
WOJCIECHOWSKA, W
SYNTHETIC COMMUNICATIONS, 1986, 16 (05) : 535 - 536
[45] BEHAVIOR OF RARE-EARTH CHLORIDES IN HEXAMETHYLPHOSPHORIC TRIAMIDE
MIKHEEV, NB
KAMENSKAYA, AN
KONOVALOVA, NA
ZHILINA, TA
ZHURNAL NEORGANICHESKOI KHIMII, 1977, 22 (07): : 1761 - 1766
[46] REACTIONS OF SEVERAL CARBONYL-COMPOUNDS WITH HEXAMETHYLPHOSPHORIC TRIAMIDE
ARIMATSU, S
YAMAGUCH.R
KAWANISI, M
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1974, 47 (06) : 1553 - 1554
[47] HEXAMETHYLPHOSPHORIC TRIAMIDE AS A SOLUBILIZING AGENT - PURIFICATION AND REACTIVATION OF DIGLYCERIDE KINASE
KONIG, B
BOHNENBERGER, E
SANDERMANN, H
FEBS LETTERS, 1981, 129 (02) : 301 - 304
[48] ELECTROCHEMICAL STUDIES IN HEXAMETHYLPHOSPHORIC TRIAMIDE .10. EFFECT OF PROTIC SOLVENTS ON THE POLAROGRAPHIC-REDUCTION OF THE ALKALI-METAL IONS IN HEXAMETHYLPHOSPHORIC TRIAMIDE
SAKURA, S
LEE, HL
FUJINAGA, T
ELECTROCHIMICA ACTA, 1980, 25 (10) : 1247 - 1250
[49] THIATIONS WITH TETRAPHOSPHORUS DECASULFIDE IN HEXAMETHYLPHOSPHORIC TRIAMIDE - SYNTHESIS OF THIOACRONYCINE AND ACRIDANETHIONES
SMOLDERS, RR
HANUISE, J
COOMANS, R
PROIETTO, V
VOGLET, N
WAEFELAER, A
SYNTHESIS-STUTTGART, 1982, (06): : 493 - 494
[50] Injection of electrons in hexamethylphosphoric triamide solutions at moderate cathodic potentials
Krivenko, Alexander G.
Komarova, Natal'ya S.
Piven, Natalia P.
MENDELEEV COMMUNICATIONS, 2007, 17 (06) : 311 - 312

← 1 2 3 4 5 →